Not likely to keep the heat in there for that long, honestly. Maybe you could get a block warmer with a battery in the car, on a timer? Charge the block warmer's battery off the house, and it's only a slight efficiency loss from the conversion of energy to the battery, then to the block warmer.
You could also consider using the second battery on a timer with a 120V inverter, as well, so you can run a slightly higher capacity block warmer. Set it on a timer to turn on about 1/2 hour before you leave school, 1 hr on colder days.
Other than that, the best you can do is insulate the hell out of the engine.
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