The roller valve train is a popular mod for reducing friction, it certainly wouldn't hurt mileage iether. Piston and head ceramic and friction reducing coatings seem like a good idea for a high output engine. Helps control heat issues. They have DIY products these days so the cost may not be too bad. I'd try it if I was rebuilding.
Be sure to play with cam timing. I advanced my Ford 2.3 OHC cam 9* and got a very noticeable boost in low-end torque. Easy and relatively cheap. Shortly after, I went to bigger and heavier wheels/tires so I can't isolate the cam timing change mileage effects.
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Good design is simple. Getting there isn't.
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