No, it doesn't work.
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Nobody has yet broken the first law of thermodynamics and there's no sign that anyone will. These laws are immutable and have withstood the test of time and many, many brilliant scientific minds.
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Hydrogen is used for power generation but it typically comes from
other sources. Hydrogen may end up being a car fuel (amongst other uses) of the future but that is purely because of convenience - unlike an EV for example you can refuel quickly. The argument is that you can use renewables to make the Hydrogen. The energy loss in making Hydrogen and then burning it is greater than using the same energy in an EV.
If you wish to try this out, I suggest you leave your car alone, try hypermiling for real results and if you are still interested get one of these.