For the needs and specifications you've given, a plug-in hybrid seems like it would be the ticket - especially a Chevy Volt (if you like Chevys and you've got over $40k to spend) or the upcoming 2012 Prius PHEV. Your wife could stay in electric mode for the commute, but have the engine there for longer trips or unexpected travel. And both these cars can handle 5 people.
The suggestions of an EV are also pretty good too. Imagine...NEVER going back to the gas station with the car you make that commute with! Wow....
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