Making alcohol is so easy that in Brazilian jails the inmates make their own booze usually out of rice, fruit peels and corn leftovers, it's called "Maria Louca" (Crazy Mary).
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Originally Posted by Xist
Isn't the higher the sugar content the better for producing alcohol? My family does not drink alcohol, so I figure that is why I do not know anything about it, except that it burns pretty!
Grape-based ethanol? Wine? 
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Sure the higher sugar content leads to a more efficient alcohol production. Regarding grape-based ethanol from Italy, since your family doesn't drink alcohol, I bet you never heard about grappa, an Italian distillate similar to the Brazilian cachaça, but made out of the mashed grape leftovers from wine production.