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I would be curious to see how the mylar technique works. It sounds like it would be a giant messy PITA, but doing fiberglass in general is a giant messy PITA, so maybe it's worth it..
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You pour the resin, squeegee over the top of the Mylar and let the resin cure before you peel the Mylar off.
I've done the same thing with paint stripper and 4mm polyethylene. The stripper melts the paint to the poly and when you peel it off the paint comes too. It's much tidier.