I wouldn't put too much into trying to improve MPGs. The 2.5L autos are stubborn. I owned a 2007 Legacy for 1 month and tried as hard as I could to get good fuel economy, and could only manage 23 MPG. That was much worse than my 2.2L manual Legacy which averaged 28 MPG. I also wasn't a fan of the sluggish auto tranny.
I'd get the alignment checked, especially if you are putting new meat on the wheels.
Don't bother with lifting the vehicle. It's already tall and capable of clearing many things. All that will do is reduce the longevity of the axles and reduce your fuel economy. If you put good chains on, you will be able to push quite a lot of snow. Other objects you can just steer around or over.
ZeroHour has
this thread detailing the extensive modding he did in his quest for 35 MPG. He only achieved 28.