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Your idea is not that crazy.
A team for the Auto X-Prize was planning to run an oxygen only combustion engine to eliminate pretty much all the emissions and to increase combustion efficiency dramatically.
It's one thing to test with bottled oxygen. It's another to run a trunk full of adsorption oxygen concentrators. Also, the use of steam injection to moderate temperatures resulted in a very large condenser otherwise miles per gallon of . . . water became a thing to watch.
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