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Does this mean thermoelectric exhaust generators as these, work better in cold climates?
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Probably not a whole lot unless that cold air is directed to the TE junction. We're talking about temperature differentials of a few hundred degrees C in general(once the car is warmed up).
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Driving in first at high rpm is the best way to heat up the exhaust. The car is burning the most fuel it can in a given time and the engine is under the least load, hence the pistons are extracting the least power from the combustion gases and the hotter the exhaust gases.
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Alright, I'll give you that one, but I sure wouldn't want to be driving around in first gear all day
JJ