Took an hour to do some further research and am adding some basic info.
Here comes the "engineering explained" smartypants:
It does not really answer the thread question about secondary catalyst function, but it is a high quality explanation.
And this good article:
How Catalytic Converters Work And Why Racers Should Play Clean | Speed Academy ... It also does not really answer the thread question, but it is otherwise interesting and thouhtful about the technology.