Honestly, the only way to answer this question is to run each fuel 1000 miles, calculate the MPG, $ per mile, and the cost-benefit ratio.
Be glad you have the option to even obtain Ethanol-less Gasoline, albeit illegally. Most people don't even have that option and gripe about it on the internet. Annoys the tar out of me because it makes me feel bad for them, truly.
Nerys is our resident "pure-Gasoline" proponent. Claims that Ethanol reduces his mileage 10-30% of his true "pure Gasoline" mileage AND killed his fuel pumps in all of his cars in very short order.
I will say this though, given the variance between tank to tank mileage, spec blending, and actual frequency of Ethanol consistency, you should not notice any difference between Gasoline with less than 10% Ethanol and Gasoline with MTBE or any other oxygenate. The only possibility is if you never ran Gasoline with Ethanol in recent history in which case it will eventually degunk your fuel tank which could clog your fuel filter or even your injectors if your fuel filter is low grade.
Paying 12% more for even 10% more mileage doesn't make logical sense to me. Now if is was higher octane and you had a sports car I could see going with Premium that just happened to be "pure Gasoline." But in my mind the only difference between Gasoline/Ethanol and pure-Gasoline is the companies you are supporting and 10% Ethanol is not a lot of support.
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-Allch Chcar
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