I was a bit lazy on my build an report these days, as my 5 year old daughter caught the flu and we all are a bit strained now; not really ill but under pressure.
Work outside is difficult to boot; cold and rain, drizzle, rain.
When I charged the batteries to full after the first use I did not open the tops to check the cells, and it had been bugging me.
Especially because I had opened the one that dropped its charge below the other two on the bottom end.
I found one cell (cell 2 of the middle pack aka 'see no voltage') was just below 3 Volt while all the other cells still held 3.18 something. I had experienced intermittent support before that; lamps would glow on start, but be cold on arrival.
It jumped right up to 3.3 Volt on charge so I let it be. Closed the box and did not look back. Stopped charging when the voltage started rising above 42.1 Volt and left it at that. That was a week ago.
Last Wednesday I did the second recharge, see previous post.
This time I did not wait for the packs to go all the way down, so no bottoming out of cells.
I wrote that post while the packs were still charging.
Wednesday charge part two
After 3 hours one of the packs (the 3rd, aka 'speak no voltage') voltage rose slightly above the other two, so I kept monitoring that as it rose gradually up to 41.6 Volt on charge.
Then the light on pack 2's charger went green. The charger does that at 43.8 Volt and cuts off. So that pack is full...
Pack one (see no voltage) goes green too. Okay.
3 stays red, the voltage climbs steadily to 42.6 Volt, adding a tenth every 5 seconds right on to 43.7 Volt. The light remains red.
Hum hey, what to make of that?
I disconnect the charger on 3 and the voltage recedes slowly to 43.4 Volt.
It is genuinely full.
If it were unbalanced then the BMS would cut the charge and balance back the overloaded cells. The voltage would drop faster than this.
Time to check the other two packs. Pack 2 is just 40.6 Volt! See no voltage, indeed! Do I have a bad cell?
Pack 1 shows 41.8 Volt right in between the other two.
When I hook them up to the charger the voltage rises 0.5 Volt, stays there for a few seconds, then climbs and shoots to the roof making the charger cut off. Then they sink back to 40.8 and 42.0 Volt respectively, which recedes to 40.6 and 41.8 after a few minutes.
That must be the BMS sensing an overcharged cell, cutting the power and balancing it gently back. At 75 mA if the specs are right.
As long as the other cells aren't full this can take a while!
But analysis based on a guess won't cut it for me this time.
Off goes the lid and the cells get a voltage check.
Indeed, one cell (cell 2 of pack 2 again) shows 3.65 Volt while the others are around 3.35 Volt.
If I hook up the charger it jumps to 3.85 Volt in a few seconds, then the BMS cuts the charge and the voltage sags one hundredth every few seconds.
So, to balance the pack I need to hook the charger up for a few seconds every 5 minutes?
I ran out of time, literally; was already burning midnight oil.
I left it at that for a couple of days.
Friday: topping off the charge
I thought it may be a good idea to help that one overly charged cell down so the other cells could be charged too.
I have a TEC to use for an electric WAI (on which I'll start work when this PHEV pack is no longer drawing all the time I want to spend on ecomodding, and more). It would draw just enough to gently discharge that cell.
It does, at about 0.5 Ampere; I can increase the draw a bit by pressing the hot edge to the cold battery case and the cold side to my fingers
Even so, the charger at 3 Ampere quickly fills it back up to cutoff.
Measuring the overall voltage reveals that the other cells are picking up though. 41.1 Volt, next cycle 41.3 Volt, then 41.8 Volt, then... 43.7???
The light on the charger stays red!
Testing the other cells, all are above 3.5 Volt. Cell 2 now is the lowest at 'just' 3.43 Volt
A few cells even venture above 3.6 Volt, but the BMS slowly brings them back in line.
A gentle discharge on a few cells sees the other cells go to 3.8 Volt at the next cycle, but all are brought back in line.
Then I discharge those a bit to test the remaining cells and BMS leads, and indeed they all get balanced down too.
The BMS top balances perfectly on all cells!
Pack one must be close to perfect balance, at 41.8 Volt.
Indeed it takes just a few cycles before it reaches 43.high and the charger remains red.
All three packs now stay red on the charger. The charger fans spin up for 3 seconds and die again, seeing no current flow in.
Conclusion:
One of my cells, cell 2 on See no voltage, has almost certainly less capacity than the rest.
While the BMS was supposed to do top balancing only, I suspect my first run drawing it low showed that it did in fact do bottom balancing too, so it gave some support every time I reconnected the packs.
But that also caused it to be the first cell to top out on recharge.
I'll try to prevent bottoming out from now on, see if that prevents the top off unbalance.
Nonetheless, the combination of the BMS and charger characteristics seem ideal.
The BMS cuts off the charge if a cell reaches 3.85 Volt and releases it again when it drops to 3.65 Volt. It will keep balancing the cell down to 3.6 Volt.
The charger cuts off at 43.8 Volt, which is 12 times 3.65 Volt.
A perfectly balanced pack will be charged to 3.65 Volt per cell, at which the pack meets the chargers max voltage so it takes no more current which makes the charger cut off.
The BMS then forces the cells to sink back to 3.6 Volt, leaving the pack at 43.2 Volt.
A slightly unbalanced pack will see some cells go higher than 3.65 Volt while some other may not even reach 3.6 Volt. But as long as the balancing current flows the chargers will maintain 43.8 Volt. So while the high cells are fighting the (then) low current flowing in, the low cells will all eventually reach 3.6 Volt, or at least get very close to that, before the charger cuts off.
A strongly unbalanced pack will cut off due to overcharge, and will keep doing that until the other cells near full charge too.
I do have a trick for that; my chargers cut off, but I can link two packs together.
One (full and balanced) pack cannot overcharge the other pack as a whole but it can recharge the unbalanced pack every time the one overcharged cells reaches its release voltage. I just have to trust the BMS will do its job.
One big reassurance is the total lack of heat development on the BMS, batteries, cables and connectors. Everything stays at ambient - even the BMS while top balancing 8 cells down at once. But that has an array of cooling fins almost as big as the palm of your hand (not mine, I have huge hand palms - and tiny fingers! Mole hands
) to dissipate about 2 Watt for that.
The only things that do produce (some) heat are the relays on the terminals and the lamps.