there's been a billion arguments about this across the net. i think the majority of folks will say that gas is gas and the only difference is the additives the various companies put in their fuel... which don't contribute (or detract) from mpgs.
for example, i put 76 in my V8 toy puller simply because it's a newer car and i want the additives in the 76 gas to keep my engine clean and what not (which the additives claim to do). in my beater commuter though i put costco gas, which i've been told has no additives.
of course, many would disagree with this assessment. LOL.
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