Quote:
Originally Posted by t vago
What exactly is this expansion ratio for water at 212 F? 1700:1?
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It isn't a fixed number.
It varies with context... temperature alone is insufficient data to determine the final expansion ratio.
Quote:
Originally Posted by t vago
That's right! 1603.35:1, not 1700:1! You're willing to continue this discussion on the basis of a rule-of-thumb figure that was not even meant for any sort of engineering at all.
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You've misunderstood me.
I'll try again.
I'm saying if you agree with either the ideal gas law or the principles it is based on ... than by confining the expansion of the steam in a limited volume container , as we have in this example ... than it follows from the ideal gas law and it's principles that the partial pressure of the steam must be higher than it would be if it's expansion were not restrained by the limited volume of the container ... to claim otherwise violates the ideal gas law and the principles it is based on.
Quote:
Originally Posted by t vago
Quote:
Originally Posted by IamIan
If the volume is not restricted it expands @212F & 14.7psi by about ~1,700:1 ... but unless I missed something the ideal gas law requires the partial pressure from the steam to go up if you confine the expansion of the same amount of steam in a limited volume
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Yah, you did miss something. I just addressed part of it, but here's the other part.
Unless there's work done on that gas after the steam is added to it, the system presented in this example will only have saturated steam. How can it possibly be otherwise? 99.9% of the water in the final system is still a liquid! And if the liquid water and the steam are at the same temperature, which must happen due to conservation of energy because no outside heat was added apart from injection of water at 100 C, and due to the fact that no compression work was performed on the system from the outside, how could there possibly be more steam added?
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This response of yours does not address the point I make in the quote you referenced from me.
Who said their is more steam added?
And as you already wrote previously ... we did compression work on the system from the outside when we added the liquid water.
The steam we have is the result of the energy that will be transferred from the initial gasses to the liquid water we put in ... Who's adding more than that?
In this part you quote from me ... I'm claiming the amount of partial pressure from phase changing a given amount of liquid water to steam will be effected by how the limits of the volume it can expand into ... which is what the ideal gas law requires.
0.96g of liquid water + 0.04 grams of steam confined to a 600cc container will not have the same pressure if the same 0.96grams of liquid water + 0.04 grams of steam is confined to a 100cc container ... the pressure will also be different if the same 0.96grams of liquid water + 0.04 grams of stream is confined to a 10cc container.
Although the ideal gas law shows this and requires this ... the mechanism for why this happens is easier to see in the kinetic theory of gasses ... although I don't see a need to go that far into the principles the ideal gas law is based on ... I think the ideal gas law should be adequate on it's own.
And honestly ... I don't understand why you seem to be arguing against the ideal gas law here???